Although we have a long ways to go before facing up to Cupid again, it seems like Emma Stone's getting ready extra-early for Valentine's Day. Last night at the NYC premiere of Friends with Benefits, the 22-year-old starlet stood out from the crowd with some bright color-blocking courtesy of a red Giambattista Valli top and a pink skirt from the same label. (Though she kept it subtle with her foot game, going with the requisite flesh-toned Christian Louboutin pumps). With her matching lipstick and bold eyes, the Vanity Fair cover girl clearly doesn't care how many hearts she breaks—and, hey, we'd be celebrating the big V everyday too if we had Andrew Garfield waiting in bed. (Just Jared)