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Cordelia & Hank, American Horror Story: Coven
Their relationship might have turned out to be, um, toxic, but Cordelia and Hank did have some hot ritual sex before it all fell apart.
Rayna & Deacon, Nashville
They get together and break up with enough frequency (and velocity) to break your neck, but when they do come together it's a powerful physical connection.
Damon & Elena, The Vampire Diaries
There were a lot of couples in this show, but Damon and Elena were always the hottest...and the most star-crossed.
When a group of people around the world find themselves mentally linked, "group sex" takes on a completely different meaning.