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The West Wing — 7 Seasons
The West Wing is the show most likely to help you when you get on Jeopardy! — possibly even more so than old reruns of Jeopardy! Besides the general government jargon that's thrown around (which will make you wish you paid more attention in your high school civics class), there's the president's constant lit and musical-theater references, as well as some geography and science facts from White House visitors. Pro tip: Qumar is not an actual country. It would have been bad diplomacy to make American TV viewers associate an actual nation with the kidnapping of the first daughter.
Frasier — 11 Seasons
Winning the coveted Family Guy distinction as the smartest show on TV, Frasier is more than just fun facts about psychology and references to operas you'll probably need to Wikipedia. It's a show you have to pay attention to, especially for physical-comedy scenes like this one.
Sherlock — 3 Seasons
If you've actually made it this long without succumbing to the pull of Benedict Cumberbatch and his scarf style, know this: Each episode of Sherlock is a challenge — a series of puzzles for you to figure out. If it's a re-watch binge, remember you're technically learning plots from pieces of classic lit (plus, watching anything with a British and/or Irish accent feels cerebral, right?).
Black Mirror — 2 Seasons
Society! Morality! Technology! Aside from being the opening of a high school slam poem, these are also things explored in this strange but addicting U.K. drama. Fair warning: It could spark an existential crisis.
House — 8 Seasons
Almost all medical shows will give you just enough tidbits to make you absolutely sure your headache is a tumor and you need 10 CCs of Epi, stat. But while Grey's Anatomy weaves some medicine around the drama, House is probably about 60-85% medicine. Who knows? Maybe you'll save your roommate a trip to the walk-in clinic and figure out what's going on with his funky rash. (Hint: It probably has to do with that poison ivy growing in your yard.)